Shimadzu LCMS-8045 CL Benutzerhandbuch Seite 139

Auto-Tuning-Ergebnisse
### Sample Information ###
Sample Type: PEG+PPG+Raffinose
### Tuning Condition ###
Detector Adjustment: On
Resolution Adjustment: On
FWHM of Spectrum: 0.70
Sensitivity Adjustment: On
Mass Calibration: On
### Tuning Result ###
Model: LCMS-8045
Interface: DUIS
Polarity: Pos
Tuning Mode: Auto
Tuning Date: 5/17/2017 10:56:35 AM
Acquisition Mode: Q1 Scan(Use CID Gas)
Nebulizing Gas Flow: 1.50(settings : 1.50) L/min
Drying Gas Flow: 0.00(settings : 10.00) L/min
### Tuning Profile ###
CD:-10.00 kV CD:-10.00 kV CD:-10.00 kV
Int.: 2965936 Int.: 2635370
FWHM: 0.63 FWHM: 0.69
m/z : 45.05 m/z : 168.10
Mag.: 6 Mag.: 7
Scan Range: 2.00 - 2000.00 Scan Speed: 30 u/s Base Peak: 445.30 (20000000)
100
256.15
300.15
168.10
100 300
m/z(Target) m/z(Actual) Difference
45.05 45.10 0.05
168.10 168.10 0.00
256.15 256.15 0.00
300.20 300.15 -0.05
652.40 652.45 0.05
1004.60 1004.65 0.05
1224.75 1224.80 0.05
1603.15 1603.10 -0.05
Const
DL Bias Const +0.0
Qarray Bias Const +0.0
Qarray RF Scan +50.0
Multipole RF Scan +100.0
Multipole1 Bias Const +0.0
Multipole1 Lens Const -0.8
Multipole2 Bias Const -0.8
Multipole2 Lens Const -1.0
Q1 Bias Const -3.5
CC Lens1 Const +0.0
CC Lens2 Const -100.0 -100.0
CC Lens3 Const -20.0
Const
CC RF Scan +200.0
CE Scan -15.0
Q3 Bias Scan -15.0
Const 107.15 1071.50 1893.40
Q1 Pre Bias Scan -15.0
Q3 Pre Bias Scan -15.0
LC/MS/MS Tuning
CID Gas Flow:
Heating Gas Flow:
Interface Bias:
Interface Current:
Interface Temp.:
DL Temp.:
Heat Block Temp.:
Q1 RF Gain:
Q1 RF Offset:
Q3 RF Gain:
Q3 RF Offset:
Q1 Post-rod Bias:
CID CELL Exit Lens:
Conversion Dynode:
Detector:
PG Vacuum:
IG Vacuum:
Corona Needle Voltage:
Corona Needle Current:
CD:-10.00 kV CD:-5.00 kV
Int.: 8448448 Int.: 6576916 Int.: 4149214
FWHM: 0.77 FWHM: 0.78
m/z : 256.15 m/z : 300.20
Mag.: 2 Mag.: 2
828.55
1004.65
652.45
500 700 900
Width Intensity
0.63 2965936
0.69 2635370
0.77 8448448
0.78 6576916
0.75 4149214
0.73 6497677
0.74 2926660
(0.83) 444852
65.05 168.10 256.15 344.20 652.40 1004.60 1893.40
+0.0 +0.0 +0.0 +0.0 +0.0
+0.0 +0.0 +0.0 +0.0 +0.0
+19.3 +50.0 +90.0 +90.0 +130.0
+30.0 +50.0 +50.0 +50.0 +300.0
+0.0 +0.0 +0.0 +0.0 +0.0
-0.8 -0.8 -0.8 -0.8 -0.8
-0.8 -0.8 -0.8 -0.8 -0.8
-1.0 -1.0 -1.0 -1.0 -1.0
-3.5 -3.5 -3.5 -3.5 -3.5
+0.0 +0.0 +0.0 +0.0 +0.0
-100.0 -100.0 -100.0 -100.0
-20.0 -20.0 -20.0 -20.0 -20.0
65.05 168.10 256.15 344.20 652.40 1004.60 1893.40
+70.0 +110.0 +130.0 +300.0 +300.0
-15.0 -15.0 -16.0 -17.0 -21.0
-15.0 -15.0 -15.1 -15.2 -15.6
-5.0 -50.0 -50.0
-5.0 -50.0 -50.0
229(settings : 230) kPa
5.01(settings : 5.00) L/Min
+4.00 kV
0.83 uA
99(settings : 100) C
250(settings : 250) C
400(settings : 400) C
4997
4970
---
---
-5.0 V
-4.0 V
-10.00 kV
-2.28(-2.28) kV
7.3e+001 Pa
2.1e-003 Pa
+4.50 kV
0.10 uA
CD:-5.00 kV CD:-10.00 kV
Int.: 6497677 Int.: 2926660
FWHM: 0.75 FWHM: 0.73 FWHM: 0.74
m/z : 652.40 m/z : 1004.60 m/z : 1224.75
Mag.: 4 Mag.: 3
1224.80
1312.80
1603.10
1100 1300 1500
+0.0 +0.0
+0.0 +0.0
+130.0 +130.0
+300.0 +300.0
+0.0 +0.0
-0.8 -0.8
-0.8 -0.8
-1.0 -1.0
-3.5 -3.5
+0.0 +0.0
-100.0 -100.0
-20.0 -20.0
+300.0 +300.0
-25.0 -25.0
-16.0 -17.0
LCMS-8045
3.8 Auto-Tuning
CD:-10.00 kV
Int.: 444852
FWHM: (0.83)
m/z : 1603.15
Mag.: 6 Mag.: 44
1893.30
1700 1900
95
LCMS-8050
CL CL
3